We demonstrate the application of molecular rotational spectroscopy to measure the conformation isomerization rate of vibrationally excited pent-1-en-4-yne (pentenyne). The rotational spectra of ...
The three exposed tyrosines of RNase A have been converted to nitrotyrosines by reaction with tetranitromethane, and the changes in the ionization properties of these nitrotyrosines have been used to ...
Chemists have long sought methods to convert more stable internal olefins into less stable terminal olefins. Isomerization reactions that proceed against a thermodynamic bias, as this one would, are ...
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